Too many infinities if you let gamma go to 1 exactly, so try making it go to 1.001 and see what happens. When you're sure of that try gamma = 1 + epsilson.
For the pressure p, you need an energy and a volume. A natural energy is the heat of vaporization for one molecule. Which should suggest a natural volume...
Moist air cools at night and the water condenses into little droplets (fog). How much water condenses? How far can a light ray travel before hitting a droplet? Use your knowledge of mean free paths from ideal gases (or use dimensions).
The Boltzmann factor gives the probability of finding a molecule in different energy states. Here the states are liquid (nice, low energy) or gas (much higher energy because all the bonds are gone).
As T goes to infinity, the vapor pressure equation predicts that
the pressure asymptotes to p
The notes for 6 Feb have everything except the diagrams. But two points to watch for: no heat flow in the adiabatic legs (2 out of the 4 steps); and the net work done must be the net heat flowing in (conservation of energy, or the first law).
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